By H Suschitzky; O Meth-Cohn; Great Britain. The Royal Society of Chemistry
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Extra info for a review of the literature abstracted between July 1980 and June 1981
Heterocycl. , 1980,17,1349. '^^ If the shorter wavelength of 254 nm was used, however, the exclusive product was (E)-(200). -Continued interest has been shown in the synthesis of cyclic carbonates (203; R', R2 = various alkyl substituents or H) by direct reaction of COz with oxirans. '62*163 Mixtures of Na, K, or Rb iodides with Mg, Al, Si, Ti, or Zr 160 16' 163 K. Murato, H. R. Jeger, Helu. Chim. Actu, 1980, 63,2212. G. R. DeMare and 0. P. Strausz, Probl. Khim. , 1979, 38 (Chem. , 1980,93, 113 546).
P. Pete, Synthesis, 1980, 895. S. Torii, K. Uneyama, M. Ono, H. Tazawa, and S. , 1979,4661. -Predictions as to the reactivities and stabilities of oxirans continue to engage the interest of theoretical chemists. ]-derivatives, quantum and molecular mechanics have been used to show that cycloheptene oxide exists in a b ~ a t - c h a iand r ~ ~cyclohexene oxide in a half-chair'" conformation. lo2 Hydrogenbonding of this type facilitates opening of the oxiran ring at either carbon atom but particularly affects C-1.
1981, 17,435 (Chem. , 1981,94,208 079). G . Kresze and M. Roessert, Liebigs Ann. , 1981,58. Meier and H. Kolshorn, 2. , Teil. 8, 1980,35,1040. 192 016). 32 Heterocyclic Chemistry Preparation of Aziridines by Cyclization. g. '~~ H OH Me0,C C0,Me MeozcwcozMe C0,Me (228) --* v C 0 , M e H (229) Two routes to 9,lO-iminophenanthrene (230) have been described. The l ~ ~ method involves the conversion of (231) into its a,a-dichloroalkyl phenyl ketimine (232) followed by its reduction by LiAlH4 in ether.
a review of the literature abstracted between July 1980 and June 1981 by H Suschitzky; O Meth-Cohn; Great Britain. The Royal Society of Chemistry